Bioethanol - Industrial world perspectives. Full text = article from Renewable Energy World Magazine May-Jun 2000

From: Subject: Bioethanol - Industrial world perspectives. Full text article from Renewable Energy World Magazine May-Jun 2000 - energy from renewable sources Date: Wed, 21 Jul 2004 17:02:57 +0200 MIME-Version: 1.0 Content-Type: multipart/related; boundary="----=_NextPart_000_0000_01C46F44.91FD91B0"; type="text/html" X-MimeOLE: Produced By Microsoft MimeOLE V6.00.2800.1441 This is a multi-part message in MIME format. ------=_NextPart_000_0000_01C46F44.91FD91B0 Content-Type: text/html; charset="iso-8859-1" Content-Transfer-Encoding: quoted-printable Content-Location: http://www.jxj.com/magsandj/rew/2000_03/bioethanol.html Bioethanol - Industrial world perspectives. Full text = article from Renewable Energy World Magazine May-Jun 2000 - energy from = renewable sources

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Bioethanol - Industrial world perspectives =

First=20 published in Renewable Energy World May-Jun 2000
=A9 = Copyright James=20 & James (Science Publishers)=20 Ltd

Given the right crops and new technology, = bioethanol could=20 make a real contribution to world fuel needs, writes G= iuliano=20 Grassi.

In the long term, potential world production of = bioethanol=20 from sugar crops could be 500 million tons per year, and = production=20 from lignocellulosic biomass could be three times as high.=20 Bioethanol could provide a contribution of 1.3 billion toe = per year=20 =96 equal to 37% of world petroleum consumption in 1998. = These are=20 impressive figures indeed.

The = 1970 energy=20 crisis stimulated research into alternative fuels, with the = aim of=20 reducing the dependency on oil in the strategic sector of = transport.=20 Today the main reason for the interest in renewable biofuels = is the=20 possibility of obtaining a substantial reduction of noxious = exhaust=20 emissions from combustion, especially as statutory limits = are=20 becoming more stringent and more exhaust components are = regulated.=20 Wider use of a chemically simple fuel such as bioethanol = will mean=20 that there are fewer harmful effects on life and ecosystems. = In=20 particular, people living in urban areas may in future = appreciate=20 the use of improved low-emission vehicles that have an = agreeable=20 smell, are smokeless and are propelled either by = reformulated=20 bioethanol, by bioethanol blended with gasoline, or by neat=20 biofuels. How the air quality can be improved is something = that is=20 increasingly worth investigating, for the sake of people and = the=20 environment!

Large-scale,=20 sustainable, worldwide production and use of bioethanol from = biomass=20 resources will produce tangible significant benefits for our = growing=20 and fast-evolving society, as well as for the earth=92s = climate.=20 Important environmental benefits could be achieved in the=20 socio-economic development of large rural populations and = the=20 diversification of energy supply, in particular for the=20 strategically vital sector of transport.

In = the very long=20 term, the estimated bioethanol world potential of 2 billion = tons per=20 year could lead to:

This bioethanol plant in Nebraska, USA, = processes corn=20 to produce 925 litres per day (Minnesota Corn Producers). = Photo:=20 Vogelbusch

A = global world=20 contribution to =91CO2 saving=92 of about 4.5 billion tons of = CO2 a year=20 (from bioethanol use alone), with further significant reduction = of=20 noxious pollutants (CO, VOCs, HC and other very dangerous = polycyclic=20 aromatic hydrocarbons) in urban areas.
An = alternative=20 renewable energy contribution of 1.3 billion toe per year (37% = of world=20 petroleum consumption in 1998 estimated at 3506 billion toe by = L=92=E9tat du=20 Monde 2000)
The = creation,=20 worldwide (mostly in rural regions) per million tons of = bioethanol per=20 year, of an estimated 85 million new jobs (production of 1 = million tons=20 per year is estimated to create 12,000 jobs for intensive=20 capital-investment activities and 73,000 jobs for = labour-intensive=20 activities, as in Brazil). This calculation does not take into = account=20 jobs created in the secondary services sector. (The total number = of jobs=20 lost in the petroleum industry, as a result of fuel = substitution, has=20 been estimated at around 2 million.)

The potential = of=20 bioethanol

CONVERSIONS:
US$1 =3D approximately 1 Euro
1 = US gallon =3D=20 3785 litres
1 ton ethanol =3D 790 kg
Heat value = =3D 6400 kcal/kg=20

In the = very long term,=20 the worldwide potential production of bioethanol is estimated to = be around=20 2 billion tons per year (0.5 billion tons per year from = sugar/starch crops=20 and 1.5 billion tons per year from lignocellulosic biomass). Of = course,=20 for high levels of market penetration the price must be relatively = low, of=20 the order of US$250 per ton. At this price level bioethanol =96 = thanks to=20 its high energy content, good environmental characteristics, the=20 socio-economic interests of rural populations and the many uses to = which=20 bioethanol can be put =96 will become a practical alternative = liquid=20 commodity, particularly of strategic interest for the vital = transport=20 sector.

A very = preliminary=20 estimation of the long-term worldwide market penetration suggests = the=20 following:

transport market=20 (20% of present consumption): 550 million tons per year=20
power = and heat=20 market (10% of the world total): power plants co-generating = capacity for=20 4,332,000 MWe and requiring about 500 million tons per year of=20 bioethanol
domestic market (in=20 both industrial and developing countries): several hundred = million tons=20 per year
chemicals market:=20 200 million tons per year.

Possible = uses of=20 bioethanol are discussed by sector later in this article. =

From the = environmental=20 point of view, bioethanol can represent a very promising = CO2-saving=20 instrument. In fact, 1 ton of bioethanol saves 2.3 tons of emitted = CO2 (as=20 well as a saving in SO2 emissions), while NOx and acetaldehydes = can be=20 controlled by existing technologies.

Future = markets for=20 bioethanol

In the = future,=20 bioethanol will become an attractive commodity =96 from an = economic and=20 environmental point of view =96 in large markets worldwide and, in = particular, in all energy markets. Bioethanol produced today on a=20 significant scale (20 billion tons per year worldwide) could in = future be=20 obtained at reasonable cost ($250/m3) in many continents as a = result of=20 the adoption of modern bioenergy complexes and dedicated crops = (the most=20 promising of which is sweet sorghum), and in the longer term = through=20 biological conversion of lignocellulosic feedstocks (expected = yield: 0.42=20 m3 per ton of dry wood). The First World Conference and Exhibition = on=20 Biomass for Energy and Industry in Seville, in June this year, = would seem=20 to provide a good opportunity for a broad discussion, in a = dedicated=20 workshop, of the following:

commercial=20 bioethanol schemes and integrated complexes=20
the = economics of=20 related bioethanol production systems=20
present = niche=20 markets and large future potential markets.

In the = future, we can=20 imagine the penetration of low-cost agricultural ethanol in = several=20 sectors:

Transport=20 market

gasoline=20 blending with neat ethanol
gasoline=20 reformulation with ETBE
bioethanol=20 reformulated fuels for diesel engines (emulsion with the = addition=20 of ignition improver)
bioethanol=20 for new generation of cars (hybrid, fuel cell, Stirling = etc.)=20
bioethanol=20 fuels for agricultural machinery.

Cogeneration=20 market

use of=20 bioethanol for abatement (through reburning) of NOx in = fossil-fuel=20 plants=20
use of=20 bioethanol as CO2 trade-off fuel
use of=20 bioethanol in steam-injection gas turbines
use of=20 bioethanol in combined-cycle power plants
use of=20 bioethanol in diesel-powered generators
use of=20 bioethanol in small cogeneration (or cooling) Stirling=20 systems=20
use of=20 bioethanol for water desalination plants (600=961000 m3 of = desalinated water from 1 ton of ethanol). =

In Hastings, Nebraska, USA, this Chief Ethanol = Fuels Inc.=20 plant produces 325,000 litres of bioethanol each day. Photo: = Vogelbusch

Domestic appliance=20 market

bioethanol fuel for=20 cooking stoves
bioethanol fuel for=20 lighting
bioethanol fuel for=20 heating and cooling devices
bioethanol for food=20 preserving (refrigeration).

Chemicals market=20

Basic = chemicals=20

ethylene (1.74 kg=20 of ethanol per kg of ethylene); ethylene markets: about 20 = million tons=20 per year in the EU and about 24 million tons per year in the = USA; with a=20 total of about 100 million tons per year worldwide, = corresponding to a=20 total potential substitution of bioethanol of 170 million tons = per year=20
hydrogen production=20
glycol = ethers=20
ethyl = acrylate=20
acetic-acid (USA=20 consumption 1.7 million tons per year; world consumption 5.5 = million=20 tons per year)
ethyl = amines=20
ethyl = acetate=20
acetaldehyde=20
ethyl = ether
ethyl + = chlorine=20 (DDT).

Intermediate=20 chemicals

surfactants=20
adhesives=20
cosmetics=20
fatty-acid=20
carbon-black=20
rubber.=20

These industrial=20 commodities derived from agriculture low-cost bioethanol can = be=20 competitive with conventional products derived from=20 hydrocarbons.

In Veracruz, Mexico, this plant (owned by = Compania=20 Azucarera Indepencia S.A.) produces 75,000 litres per day = from cane=20 molasses. Photo: = Vogelbusch

Forecast of=20 bioethanol economics

The use, = for the=20 production of renewable energy, chemicals, materials and = commodities, of=20 agricultural feedstocks from cultivation in set aside areas = (20=9630 million=20 ha in the USA, 5 million ha in the EU) or in even larger available = marginal areas worldwide will have a large positive impact: =

on = rural=20 development (new jobs and supplementary incomes)
on = general and=20 local environmental degradation, for example mitigation of=20 greenhouse-gas effects and the reduction of pollution in urban = areas.=20

Integrating the=20 production of food, feed and biofuels should maximize the = industry=92s=20 economic activity, and facilitate its adaptation to market = fluctuations.=20 In particular, this concept is suitable for the production of = bioethanol=20 as a co-product and the simultaneous production of power, heat, = DDG=20 (Distilled Derived Grain animal feed), bioethanol and industrial=20 commodities (paper, board and panels, organic fertilizers, etc.). = Several=20 uses of bioethanol in the large energy and primary/intermediate = chemicals=20 markets would appear to be cost-competitive with conventional = products=20 from hydrocarbons, if bioethanol is available at a price around = $250/ton.=20

Total = world production=20 of sugar, from 1.1 billion tons per year of sugar cane (17.6 = million ha)=20 and 0.26 billion tons per year of sugar beets is presently about = 216=20 million tons per year. Long-term, potential world sugar yield from = suitable excess croplands (995 million ha according to an FAO = evaluation)=20 cultivated with starch-sugar crops can be estimated as roughly:=20

EU: = about 200=20 million tons per year
USA: = about 500=20 million tons per year
rest of = the=20 world:800 million tons per year.

This means = a total=20 bioethanol production of 0.75 billion tons per year (500 million = toe per=20 year). While this represents only 6% of the actual world primary = energy=20 needs (9 billion toe per year), it represents 21% of world needs = when=20 compared with present petroleum consumption (3.5 billion tons per = year in=20 1998).

3D"Pekin
Pekin Energy Company=92s bioethanol plant, = Illinois, USA=20 produces over a million litres of bioethanol per day. Photo: = Vogelbusch

However, when=20 commercial production of bioethanol from lignocellulosic = biomass (by=20 enzymatic processing) becomes available (perhaps in 5=9610 = years), the=20 potential bioethanol production and market interest will = increase=20 considerably, since production of lignocellulosic biomass = worldwide=20 is ten times that of other types of biomass. Some US = forecasts=20 anticipate a marginal cost for bioethanol of around $180 per = m3=20 ($0.67/gallon).

At = present, two=20 thirds of world sugar production are obtained from = sugar-cane and=20 one third from sugar beet. These two crops are not in = competition,=20 but complementary, being cultivated for their specific = requirements=20 in two different climatic belts. In contrast, sweet sorghum = can be=20 cultivated in temperate and tropical regions, increasing its = potential benefits. Other crops that can yield = oligosaccharides=20 (potatoes, cereals, grapes, etc.) are generally not much = utilized=20 for bioethanol production (with the exception of corn in the = USA).=20 However, particular varieties of sweet sorghum recently = developed in=20 China, the USA, and the EU have very attractive and = economically=20 promising characteristics: =

Sweet = sorghum can=20 be grown in temperate and tropical regions; it needs only an = accumulated=20 daily temperature, above 10=B0C, of at least 2600=B0=964500=B0C = during the 4=965=20 month plant cycle).
Sweet = sorghum=20 produces a very high yield in terms of grains, sugar, = lignocellulosic=20 biomass (on average a total of 30 dry tons/ha per year) in = low-quality=20 soils, with much lower inputs of fertilizers and irrigation = water than=20 other crops (200 tons water per dry ton of crop =96 half of that = required=20 by sugar beet and a third of the requirement for sugar cane or = corn).=20 The total yield of bioethanol can reach 5 m3/ha per year. =
Plantations need=20 less seed than for other crops: 15 kg/ha compared with 40kg/ha = for corn,=20 or 150 kg/ha for wheat.

The = advantages of=20 sweet sorghum for the production of bioethanol can be seen in = Tables 1 and=20 2.

TABLE 1.=20 Yields and mineral losses for various crops=20
Type of = crop=20	Sugar=20 yield (tons/ha)	Mineral loss per ton of crop (kg) =
N =	P2O5 =	K2O =
Sugar=20 cane	8-12=20	1	0.1	2
Sugar=20 beet	6-8=20	5	1-2	5-6
Potatoes	2-5=20
Sweet=20 sorghum	7-12=20	0.9	0.9	1.3
Corn	5-8=20	10	4	5
Wheat	2.5-4.5
Cassava	3=20
Grapes	0.7=20
Lignocellulosics	9-22=20

TABLE 2.=20 Estimated prices for bioethanol produced from different=20 crops
Crop	Price of=20 bioethanol (US$/m3)	Energy=20 ratio (out/input =96 bioethanol only) =
Sugar=20 beet (15 Euros/ton)	300-400	1.76
Sugar=20 beet (15 Euros/ton)	690=20	1.76
Sugar=20 cane	260=20	2.42
Sweet=20 sorghum	200-300	2.23 (only ethanol)
Potatoes	990=20	1.7
Corn=20 (120 $/ton)	300-420	1.3
Wheat=20 (140 $/ton)	770
Cassava	790=20	1.73
Lignocellulosics (acid hydrolysis)	450=20
Lignocellulosics (enzymatic hydrolysis)	180=20
Synthesized ethanol	540=20	0.75

It is = expected that=20 bioethanol from sweet sorghum can be co-produced in the EU = (central and=20 south-east regions) at a marginal cost of about $250/m3. The = selling value=20 of bioethanol produced in integrated complexes with sweet-sorghum=20 plantations will depend on the market value of the other = co-products=20 (heat, electricity, DD, etc.) and possible support from = investments that=20 are sometimes available (e.g. from structural funds) to create = permanent=20 jobs.

The = following is a=20 very preliminary evaluation of the economics concerning a = bioenergy=20 complex, based on:

a = plantation of=20 sweet sorghum of 8500 ha
a = bioethanol plant=20 producing 50,000 m3/year
a = cogeneration=20 plant producing 28 MWe + 56 MWth
a DDG = (dried=20 derived grain) production of 13,000 tons per year
a = specific=20 investment for cogeneration of $1400 per kWe
a = specific=20 investment for bioethanol of $700/m3 produced per year
a = specific=20 investment for DDG plant of $250 per ton of DDG. =

Figures 1 = and 2 show=20 the interrelation production costs and the effect of an = interrelation=20 investment grant on the production cost of ethanol.

FIGURE 1.=20 Interrelation production costs for ethanol, heat and=20 power

FIGURE 2. The=20 effect of an interrelation investment grant on the = production cost=20 of ethanol

For = example in=20 Germany, with a selling price of bioelectricity of $0.1/kWh (by = law, March=20 2000) and zero value for heat, bioethanol from sweet sorghum, as a = co-product, has a marginal cost of about $150 per ton ($120/m3).=20

In = southern Italy,=20 with a bioelectricity price of $0.08/kWhe and an investment grant = of 50%=20 (from EC Regional Funds), the marginal cost of bioethanol is = estimated at=20 around $135 per ton ($110/m3). At these prices, bioethanol can = penetrate=20 many sectorial applications and markets as discussed = below.

Specific uses of=20 bioethanol

A summary = of different=20 possible markets.

The = transport=20 market =96 blending, ETBE reformulation

Ethanol is = used in=20 blends with gasoline at 10=9685% in volume (E10-E85), which = contain about=20 3.5% wt of oxygen. Usually the blends are obtained by =91splash=92 = blending=20 ethanol with unleaded gasoline, already in the distribution = system, to=20 meet the requirements for higher-grade gasoline.

Ethanol = has already=20 been approved in the USA for in RFG (reformulated gasoline) up to = a 2.0%=20 oxygen level, but the final fuel characteristics must meet other=20 specifications, including vapour pressure. Figure 3 shows the = correlation=20 between the price (at the refinery gate) of gasoline just refined = (without=20 additives) with that of crude oil.

In the = longer term, or=20 when indirect but real costs are taken into account (e.g. = CO2=96SO2=20 trade-off), bioethanol could approach a price lower than the = production=20 cost of gasoline, thus satisfying the requirements of refiners for = a=20 significant penetration of bioethanol as an additive in the EU = Gasoline=20 Pool (80=9690% of premium gasoline prices). A second important = requirement=20 is the guarantee of supply. A positive demonstration had been = carried out=20 in Brazil. At present, bioethanol must be considered in = competition with=20 methanol (although there are pending actions in USA to ban = methanol=20 because of the health risk deriving from potential ground-water=20 contamination). As methanol presently costs $150 a ton ($0.46 per = gallon),=20 including transport and duty, even if the higher heat content = value of=20 bioethanol is not taken into account, it appears that in some = situations=20 bioethanol could already penetrate the transport fuel market. =

Bioethanol = has also=20 been blended in diesel fuels up to 95% (vol.) of ethanol. This = fuel should=20 have about the same overall transport efficiency (a loss of only = 10% ) as=20 diesel fuel in compressed ignition engines, but ethanol must be = perfectly=20 dry or an emulsifying addictive must be used to maintain = solubility.=20 Low-cost bioethanol could be conveniently used in new generation = cars,=20 i.e. hybrid cars with optimized ethanol engines (expected in about = 2004),=20 or fuel-cell cars or Stirling engine cars. Bioethanol-blended = diesel fuels=20 could be useful in fulfilling EC recommendations concerning the = emissions=20 from agricultural machinery.

Bioethanol = also=20 represents a good alternative to 100 low-lead aviation gasoline = for=20 piston-engine-aircraft (tourism), for the preparation of unleaded = fuel=20 with a minimum motor octane of 98, as recommended by the US = General=20 Aviation Manufacturers Association. Ethanol was used extensively = by=20 Germany, Japan and Italy during the Second World War. Research and = the=20 development of ethanol as aviation fuel has been undertaken over = the past=20 20 years at the Renewable Aviation Fuels Development (RAFD) Center = at=20 Baylor University in the USA. Nine aircraft modified for ethanol = have=20 accumulated about 2500 hours of flying time. This programme has = been able=20 to demonstrate that:

100% = denaturated=20 ethanol is the ideal fuel to replace 100 low lead aviation = gasoline=20
that = the fuel is=20 reliable; several aircraft engines have received Federal = Aviation=20 Administration (FAA) certification to use ethanol; in the case = of use of=20 a new fuel, both the engine and the frame of any aircraft to be = engaged=20 in civil commercial operation must be licensed in the certified = category=20 and must obtain a Supplementary Type Certificate (STC). =

Pure ETBE = (containing=20 46% bioethanol and 54% isobutylene) could perhaps be utilized as = jet-fuel=20 (world market at present about 150 Mtoe per year). The RAFD Center = is=20 pursuing a research programme on this alternative fuel for gas = turbines.=20

The = power and heat=20 markets

In = fossil-fuel plants=20 abatement of NOx is obtained by reburning other fuels (such as = natural=20 gas) in a secondary zone of the combustion chamber. An oxygenated = fuel=20 like bioethanol could be a good reburning fuel. It would be useful = to=20 assess the efficiency and the =91economic values=92 of bioethanol = as a=20 NOx-reducing fuel, with its potential value as a =91CO2-neutral = fuel=92 also=20 taken into account; for example:

$100 per=20 ton as fuel value + $50 per ton as CO2 saver + $50 per ton as = SO2 saver=20

indicating = that, at=20 $250/m3 the use of agricultural bioethanol is feasible for this = market,=20 which is much larger than the transport market.

Bioethanol = could also=20 be used in steam-injection gas turbines (aero derivative) to = satisfy=20 =91peak-load=92 requirements. The relative high values of the peak = bioelectricity (twice the base value), the high efficiency (40%) = and=20 simplicity of the generator, together with the limited cost of = specific=20 investment ($600=96800 per kWe) may render possible the use of = bioethanol=20 for an operation-time of 3000=964000 hours per year.

Bioethanol = could be=20 used in gas-turbine/steam-turbine combined-cycle power generators. = With an=20 inlet gas-turbine temperature of 1200=B0C, an outlet temperature = of 500=B0C=20 and a steam pressure of 50 bar, a total efficiency of about 48% is = expected. Specific investment is likely to be: about $800 per kWe = (20=9640=20 MW range); heavy-duty 50 MWe $700 per kWe, efficiency 50%; 200 MW = $500 per=20 kWe, efficiency 55%, NOx emission level 50 ppm.

High = bioethanol (95%)=20 blended-reformulated fuels for diesel could be of great interest = for=20 small, medium and large diesel generators, in particular for = operation on=20 remote sites and in developing countries (they could be of great = interest=20 for food preserving, water purification etc.).

The = domestic=20 appliances market

In = developing=20 countries especially, bioethanol could be of great economic and=20 environmental interest for cooking and lighting as a substitution = for LPG=20 (particularly for remote locations). For cooking, the average = annual=20 amount of bioethanol needed is estimated at around 80=96100 litres = per=20 person.

The = chemicals=20 market

As = previously=20 indicated, there are likely to be good opportunities for the = production of=20 wide varieties of chemical commodities from bioethanol when the = price of=20 bioethanol is low (competitive with hydrocarbon feedstocks). A = detailed,=20 specialist analysis is required. The following data concerns = ethylene,=20 which represents a large-volume commodity that could be profitably = derived=20 from agricultural bioethanol: at present the chemical industry, = which=20 depends on ethylene, is evaluating the possibility of utilizing = ethanol to=20 produce ethylene according to the following dehydration process:=20

C2H5=96 = OH =3D C2H4 +=20 H2O.

This = process is=20 already used on a commercial scale in Brazil to reduce oil = imports. In=20 reality, the ethylene market is very large and could represent an=20 attractive and fascinating challenge for agricultural bioethanol, = because=20 of the two very important advantages of bioethanol-based=20 processes:

The = investment=20 required is greatly reduced.
There = is an absence=20 of undesired co-products from the bioethanol process (in the = nafta=20 cracking process for example, the co-products such as propylene, = butane,=20 butadiene are not always desired). Other competitive processes = could,=20 however, be available from synthesis of gas and from = methanol.=20

Conclusion=20

Bioethanol = will become=20 a significant strategic, environmentally important liquid fuel = when it can=20 be produced at a marginal cost of about $250/m3 =96 this is a = pre-condition=20 for large market penetration in many sectors. It is important, = therefore,=20 to identify ways of producing bioethanol at this low cost. Two = options=20 seem to offer such conditions:

integrated=20 processing of specific high-yield C-4 Crops, such as sweet = sorghum=20 (already a commercial possibility now)
biological=20 enzymatic processing and fermentation of lignocellulosic biomass = (in the=20 medium term).

A broad = and deep=20 assessment is required to identify the short-, medium- and = long-term=20 commercial opportunities so that penetration of the potential = markets can=20 be initiated as soon as possible. The potential long-term = worldwide=20 production of bioethanol from sugar crops is estimated at around = 500=20 million tons per year and the potential production from = lignocellulosic=20 biomass could reach three times that figure.

Giuliano Grassi is Secretary General of the = European=20 Biomass Industry Association (EUBIA), Brussels, Belgium.
Fax: = 32 2 28=20 28 424
e-mail: eubia.brussels@pophost.eu= net.be=20

Back= to=20 the top

=A9 James & James (Science Publishers) Ltd 1996 - = 2000. All=20 rights reserved.
James & James, 8-12 Camden High Street, = London NW1=20 0JH, UK; Tel +44 20 7387 8558 Fax +44 20 7387 8998.
email James &=20 James.

Page last updated 22nd June=20 2000

The=20 James & James web site is edited by O'Mahoney Associates=20 Ltd.
O'Mahoney Associates also provide the specialised = information=20 management and database services for the web and the paper = editions of the=20 James & James company listings, directories as well as = subscription=20 management services for its journals. email O'Mahoney=20 Associates.

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